@article{MAKHILLJEAS2018131416573,
title = {Corrosion Behaviour of Mild Steel in 0.5 M Sulphuric Acid
Media in the Presence of Potassium Chromate},
journal = {Journal of Engineering and Applied Sciences},
volume = {13},
number = {14},
pages = {5789-5795},
year = {2018},
issn = {1816-949x},
doi = {jeasci.2018.5789.5795},
url = {https://makhillpublications.co/view-article.php?issn=1816-949x&doi=jeasci.2018.5789.5795},
author = {Joshua,Cleophas,Jacob,Olugbenga and},
keywords = {adsorption isotherm,Tafel slope,potentiodynamic polarization,weight loss,Corrosion,physical,adsorption},
abstract = {This research investigates the behaviour of K2CrO4 on mild steel corrosion in 0.5 M H2SO4 at ambient temperature of 30C. The study was conducted using weight loss and potentio-dynamic polarization
measurements. Data were recorded from the weight loss tests while the readout from the potentiostat was
documented. Adsorption studies were also carried out. Furthermore, an investigation was conducted using
surface coverage against concentration plot to determine when the best surface would be obtained during the
experiment. Results from the study revealed that inhibitor efficiency increased as inhibitor concentration
increased. The potentio-dynamic polarization plot also identified the inhibition mechanism of action as mixed
but predominantly anodic type inhibition with maximum Ecorr displacement of 68 mV. The adsorption of the inhibitor agrees with the Langmuir adsorption isotherm while the separation factor which is a component of the
Langmuir expression showed a favourable adsorption. The Gibbs free energy of adsorption showed negative
value (-9.8 kJ/mol) depicting a spontaneous process with a prevalence of physical adsorption. The first day
curve showed the best surface coverage values across all inhibitor concentrations utilized.}
}