TY - JOUR
T1 - Potentiometric Studies of Nickel (II), Copper (II) and Cobalt (II) Binary Complexes with Glycine Amino Acid in Aqueous Solution
AU - Sadat Neiband, Marzieh
JO - Journal of Engineering and Applied Sciences
VL - 11
IS - 6
SP - 1306
EP - 1310
PY - 2016
DA - 2001/08/19
SN - 1816-949x
DO - jeasci.2016.1306.1310
UR - https://makhillpublications.co/view-article.php?doi=jeasci.2016.1306.1310
KW - Potentiometric study
KW -nickel (II)
KW -copper (II)
KW -cobalt (II)
KW -glycine
KW -complexe formation
AB - The complexation equilibria of glycine with some transition metal ions such as Cu2+, Co2+ and Ni2+ were studied by potentiometric method in aqueous solution. All of the titration steps were carried out at 25.0±0.1°C and ionic strength (μ) of 0.1 M supported by NaNO3. The overall stability constants logβs of respective species were evaluated by computer refinement of the corresponding potentiometric pH titration data using BEST computer program. The corresponding distribution diagrams were depicted as a function of pH by using SP and SPE programs. The most likely species were obtained from distribution diagrams. Complex stabilities follow the trend copper(II)>nickel(II)>cobalt(II) which is in agreement with the Irving-Williams series.
ER -