Sobhy M. Yakout, Ashraf A. Mostafa,
Removal of Nitrite from Aqueous Solution by Active Carbon: Adsorption Kinetics Modeling,
Journal of Animal and Veterinary Advances,
Volume 13,Issue 9,
2014,
Pages 558-563,
ISSN 1680-5593,
javaa.2014.558.563,
(https://makhillpublications.co/view-article.php?doi=javaa.2014.558.563)
Abstract: Nitrite is formed naturally by the nitrogen cycle during the process of nitrogen
fixation in vertebrates, nitrate is converted to nitrite and other metabolites
(nitric oxide and N-nitroso compounds). Overall, the acute toxicity of nitrite
has been shown to be ~10 fold higher than that of nitrate. In this study, KMnO4
oxidized Rice straw activated carbon has been used for nitrite removal
from aqueous solution. Both unoxidized and oxidized carbon samples are characterized
using N2-adsorption, elemental analysis, Boehms titration and
surface fractal dimension. Results show that oxidation treatment enhanced surface
area and pore volume. The modified carbon good nitrite adsorption compared to
unoxidized one. The equilibrium was attained after shaking for about 10 h beyond
which there is no further increase in the adsorption. The pseudo first and second
order kinetic models were applied assuming that the external mass transfer can
be neglected and the process is chemisorption controlled.
Keywords: Adsorption;Rice straw;nitrite;active carbon;treatment