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Research Journal of Applied Sciences

ISSN: Online 1993-6079
ISSN: Print 1815-932x
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Synthesis and Characterization Spectroscopic of the Chiral 1, 3-Oxazolidines

M. Dali , H. Boudiaf and A. Boukhari
Page: 759-762 | Received 21 Sep 2022, Published online: 21 Sep 2022

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Abstract

The condensation of para-substituted aromatic aldehydes with 1, 2-aminoalcohols such as (L)-prolinol, gives 1, 3- oxazolidines (potential proinsecticides). Starting of (S) amino alcohol, thanks to asymmetric carbone C2, we can obtain (S, S) and (S, R) diastereoisomers. The substituent situated on para position to aldehyde function in aromatic ring, affects the obtained proportion on diastereoisomers. If it is an electro-donor, the (S, S) diastereoisomer is clearly dominent; if it is an electro-attractor, the proportion of (S, S) and (S, R) diastereoisomers is practically the same.


How to cite this article:

M. Dali , H. Boudiaf and A. Boukhari . Synthesis and Characterization Spectroscopic of the Chiral 1, 3-Oxazolidines.
DOI: https://doi.org/10.36478/rjasci.2007.759.762
URL: https://www.makhillpublications.co/view-article/1815-932x/rjasci.2007.759.762